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Q.1
WBCS Prelims 2023
Baking soda is a mixture of
A.sodium carbonate and acetic acid
B.sodium carbonate and tartaric acid
C.sodium hydrogen carbonate and tartaric acid
D.sodium hydrogen carbonate and acetic acid
Explanation
Why Correct: Commercial baking powder contains sodium hydrogen carbonate (baking soda) and tartaric acid, which react when moist to produce carbon dioxide for leavening. Distractor Analysis: Sodium carbonate is washing soda, not used in baking powder. Acetic acid is vinegar acid, not typically used in dry baking powder mixtures. Takeaway: Baking soda alone is sodium hydrogen carbonate; baking powder includes both baking soda and an acid like tartaric acid or cream of tartar.
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Q.2
WBCS Prelims 2019
Select the one having pH < 7
A.Lemon juice
B.Lime water
C.Human blood
D.Antacid
Explanation
Why Correct: Lemon juice contains citric acid with a pH around 2.2-2.4, making it acidic. Distractor Analysis: Lime water is calcium hydroxide solution with pH 10.5-12.4, human blood maintains pH 7.35-7.45, and antacids like magnesium hydroxide have pH 10-11. Takeaway: Vinegar has pH 2.4-3.4, while gastric juice has pH 1.5-3.5.
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Q.3
WBCS Prelims 2019
To protect tooth decay we are advised to brush our teeth regularly. The nature of the toothpaste commonly used is
A.acidic
B.neutral
C.basic
D.corrosive
Explanation
Why Correct: Toothpaste contains basic compounds like sodium bicarbonate or calcium carbonate that neutralize acid produced by bacteria. Distractor Analysis: Acidic substances would accelerate enamel erosion, neutral toothpaste lacks cleaning effectiveness, and corrosive materials would damage oral tissues. Takeaway: Fluoride in toothpaste strengthens enamel by forming fluorapatite, which resists acid attack better than hydroxyapatite.
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Q.4
WBCS Prelims 2018
Chemical name of vinegar is
A.Sodium nitrate
B.Dilute acetic acid
C.Chloride of lime
D.Calcium
Explanation
Why Correct: Vinegar is 5-8% acetic acid (CH3COOH) in water, produced through fermentation of ethanol by acetic acid bacteria. Distractor Analysis: Sodium nitrate is NaNO3, a preservative in processed meats. Chloride of lime is Ca(OCl)2, bleaching powder used for disinfection. Calcium is a metallic element (Ca), not vinegar. Takeaway: Acetic acid glacial is 99-100% pure, while vinegar contains 5-8% acetic acid plus flavor compounds from fermentation.
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Q.5
WBCS Prelims 2015
The compound that cannot be kept in glass vessel because it reacts with glass is
A.HNO3
B.HCl
C.HF
D.HBr
Explanation
Why Correct: Hydrofluoric acid (HF) reacts with silicon dioxide (SiO2) in glass to form silicon tetrafluoride gas and water, dissolving the glass. The reaction is: SiO2 + 4HF -> SiF4 + 2H2O. Distractor Analysis: Nitric acid (HNO3) is a strong oxidizing acid but does not attack glass significantly. Hydrochloric acid (HCl) is a strong acid but does not react with glass. Hydrobromic acid (HBr) is similar to HCl and does not attack glass. Takeaway: HF is stored in plastic containers like polyethylene or Teflon, never in glass. It also causes severe tissue burns that penetrate deeply.
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Q.6
WBCS Prelims 2014
Washing soda is the common name for
A.Sodium carbonate
B.Calcium carbonate
C.Sodium bicarbonate
D.Sodium hydroxide
Explanation
Why Correct: Washing soda is sodium carbonate decahydrate (Na2CO3·10H2O), a water-softening agent used in laundry and cleaning. Distractor Analysis: Calcium carbonate (CaCO3) is limestone, chalk, and marble, used in construction and antacids. Sodium bicarbonate (NaHCO3) is baking soda, a leavening agent and mild antacid. Sodium hydroxide (NaOH) is caustic soda, a strong base used in soap making and drain cleaners. Takeaway: Baking soda (NaHCO3) releases CO2 when heated or mixed with acid, while washing soda (Na2CO3) does not produce gas and is more alkaline.
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Q.7
WBCS Prelims 2013
Muriatic acid used in household work is diluted form of –
A.Acetic acid
B.Hydrochloric acid
C.Oxalic acid
D.Aqua regia
Explanation
Why Correct: Muriatic acid is the common name for commercial-grade hydrochloric acid (HCl), typically diluted to 20-30% concentration for cleaning and descaling. Distractor Analysis: Acetic acid is vinegar (CH3COOH). Oxalic acid is a cleaning agent for rust stains. Aqua regia is a mixture of concentrated nitric and hydrochloric acids used to dissolve gold. Takeaway: Hydrochloric acid is also called spirits of salt because it can be produced by reacting salt (NaCl) with sulfuric acid.
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Q.8
WBCS Prelims 2001
Vinegar is a dilute solution of
A.formaldehyde
B.formic acid
C.ethanol
D.acetic acid (CH3COOH)
Explanation
Why Correct: Vinegar contains 4-8% acetic acid (CH3COOH) in water, produced through fermentation of ethanol by acetic acid bacteria. Distractor Analysis: Formaldehyde is a preservative and disinfectant, not found in vinegar. Formic acid occurs in ant venom and some industrial processes, but vinegar uses acetic acid. Ethanol is the starting material for vinegar production through fermentation, but vinegar itself contains acetic acid. Takeaway: Acetic acid gives vinegar its sour taste and pungent smell, while the fermentation process converts ethanol to acetic acid via oxidation.
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Q.9
WBCS Prelims 2001
A pair of compounds that cannot exist together in a solution is
A.sodium bicarbonate and caustic soda
B.sodium bicarbonate and water
C.sodium bicarbonate and sodium carbonate
D.sodium carbonate and caustic soda
Explanation
Why Correct: Sodium bicarbonate (NaHCO3) reacts with caustic soda (NaOH) in a neutralization reaction to form sodium carbonate (Na2CO3) and water, preventing coexistence. Distractor Analysis: Sodium bicarbonate dissolves in water without chemical reaction. Sodium bicarbonate and sodium carbonate can coexist as both are sodium salts in equilibrium. Sodium carbonate and caustic soda can coexist as both are basic compounds without direct reaction. Takeaway: Bicarbonate ions (HCO3-) act as weak acids that react with strong bases like hydroxide ions (OH-) to form carbonate ions (CO3^2-).
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Q.10
WBPSC Miscellaneous Prelims 2012
‘Vanishing colour’ may be prepared by mixing phenolphthalein with
A.carbon dioxide water
B.sulphurous acid
C.dilute solution of caustic soda
D.dilute ammonia solution
Explanation
Why Correct: Phenolphthalein turns pink in basic solutions and colourless in acidic or neutral solutions. Dilute ammonia is a weak base that initially gives a pink colour, but as ammonia evaporates the solution becomes neutral and the colour fades, creating a ‘vanishing colour’ effect. Distractor Analysis: Carbon dioxide water (carbonic acid) and sulphurous acid are acidic – phenolphthalein remains colourless, so no vanishing colour occurs. Dilute caustic soda is a strong base that gives a stable pink colour that does not vanish without adding an acid. Takeaway: Phenolphthalein is a pH indicator: colourless in acidic/neutral (pH 10). A volatile base like ammonia produces a temporary pink that fades upon exposure to air.
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Q.11
WBPSC Miscellaneous Prelims 2011
An acid in concentrated form does not give brown fumes with copper turnings and when dilute gives a curdy white precipitate with silver nitrate solution and the precipitate is soluble in ammonia solution, but insoluble in nitric acid. The acid is
A.Nitric acid
B.Hydrochloric acid
C.Sulphuric acid
D.Phosphoric acid
Explanation
Why Correct: Concentrated HCl does not produce brown fumes (NO2) with copper. Dilute HCl gives a curdy white precipitate of AgCl with AgNO3. AgCl dissolves in NH3 forming [Ag(NH3)2]+ but remains insoluble in HNO3, confirming the presence of chloride ions. Distractor Analysis: Concentrated HNO3 reacts with copper to produce brown NO2 fumes, so it does not match the first condition. Dilute H2SO4 forms a slightly soluble white precipitate of Ag2SO4 with AgNO3, but it is not curdy and dissolves in water, not specifically in NH3; also concentrated H2SO4 does not fume with Cu. Dilute H3PO4 gives a yellow precipitate of Ag3PO4 with AgNO3, not white; concentrated H3PO4 does not fume with Cu. Takeaway: The AgCl solubility test (white curdy precipitate soluble in NH3, insoluble in HNO3) is a definitive identification of chloride ions. In exams, combine the 'no brown fumes with Cu' test to rule out oxidizing acids like HNO3.
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Q.12
WBPSC Miscellaneous Prelims 2010
A drop of phenolphthalein is added to a colourless liquid, but no change in colour takes place. The liquid, therefore, is
A.basic
B.acidic
C.neutral
D.acidic or neutral
Explanation
Why Correct: Phenolphthalein remains colorless in acidic and neutral solutions (pH 10). Since no color change occurred, the liquid is either acidic or neutral. Distractor Analysis: A basic solution would turn phenolphthalein pink. "Acidic" alone is incomplete because neutral solutions also cause no change. "Neutral" alone ignores acidic possibilities. Takeaway: Phenolphthalein is a common indicator: colorless in acidic/neutral, pink in basic. Its pH range is 8.2-10.0 for the color change.
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Q.13
WBPSC Miscellaneous Prelims 2008
Anhydrous CaO may be used to dry:
A.H2S gas
B.NH3 gas
C.CO2 gas
D.HCl gas
Explanation
Why Correct: Anhydrous calcium oxide (CaO) is a basic drying agent that absorbs water without reacting with basic gases like ammonia (NH3). Therefore, it is suitable for drying NH3. Distractor Analysis: H2S, CO2, and HCl are acidic gases. CaO reacts with them (e.g., CaO + CO2 -> CaCO3; CaO + 2HCl -> CaCl2 + H2O), so it would remove them rather than simply drying. Takeaway: Basic drying agents (like CaO, NaOH) can only dry basic or neutral gases. Acidic gases require acidic drying agents like concentrated H2SO4 or P2O5.
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Q.14
WBPSC Miscellaneous Prelims 2008
Aqua regia is a mixture of:
A.One part HNO3 and three parts HCl
B.Three parts HNO3 and one part HCl
C.One part H2SO4 and three parts HCl
D.Three parts H2SO4 and one part HCl
Explanation
Why Correct: Aqua regia is a 1:3 volumetric mixture of concentrated nitric acid (HNO3) and concentrated hydrochloric acid (HCl). This specific ratio produces nitrosyl chloride and chlorine, enabling dissolution of noble metals. Distractor Analysis: Three parts HNO3 and one part HCl reverses the ratio and does not form the active species for metal dissolution. Sulfuric acid (H2SO4) mixtures, in any proportion, produce different oxidizing conditions and are not used as aqua regia. Takeaway: Remember the ratio as "three parts HCl to one part HNO3" – a mnemonic is that hydrochloric acid (HCl) is the major component by volume.
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Q.15
WBPSC Miscellaneous Prelims 2007
The colour of alkaline phenolphthalein solution is
A.blue
B.deep pink
C.violet
D.green
Explanation
Why Correct: Phenolphthalein is an acid-base indicator that remains colorless in acidic and neutral solutions (pH 8.2), it ionizes to form a colored anion, producing a deep pink color. Distractor Analysis: Blue is characteristic of other indicators like bromothymol blue in alkaline medium, not phenolphthalein. Violet is not a typical indicator color for phenolphthalein; it may appear in certain solvents but not in aqueous alkaline conditions. Green is not observed with phenolphthalein; it is a combination color from other indicators. Takeaway: Phenolphthalein is colorless in acidic/neutral and pink (deep pink) in basic. Its pH transition range is 8.2–10.0. Common memory aid: "Pink in base, colorless in acid."
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