HomePYQChemistryAcids, Bases & Salts
Acids, Bases & Salts
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Q.1
WBCS Prelims 2023
Baking soda is a mixture of
A. sodium carbonate and acetic acid
B. sodium carbonate and tartaric acid
C. sodium hydrogen carbonate and tartaric acid
D. sodium hydrogen carbonate and acetic acid
Explanation
Why Correct: Commercial baking powder contains sodium hydrogen carbonate (baking soda) and tartaric acid, which react when moist to produce carbon dioxide for leavening.
Distractor Analysis: Sodium carbonate is washing soda, not used in baking powder. Acetic acid is vinegar acid, not typically used in dry baking powder mixtures.
Takeaway: Baking soda alone is sodium hydrogen carbonate; baking powder includes both baking soda and an acid like tartaric acid or cream of tartar.
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Q.2
WBCS Prelims 2019
Select the one having pH < 7
A. Lemon juice
B. Lime water
C. Human blood
D. Antacid
Explanation
Why Correct: Lemon juice contains citric acid with a pH around 2.2-2.4, making it acidic.
Distractor Analysis: Lime water is calcium hydroxide solution with pH 10.5-12.4, human blood maintains pH 7.35-7.45, and antacids like magnesium hydroxide have pH 10-11.
Takeaway: Vinegar has pH 2.4-3.4, while gastric juice has pH 1.5-3.5.
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Q.3
WBCS Prelims 2019
To protect tooth decay we are advised to brush our teeth regularly. The nature of the toothpaste commonly used is
A. acidic
B. neutral
C. basic
D. corrosive
Explanation
Why Correct: Toothpaste contains basic compounds like sodium bicarbonate or calcium carbonate that neutralize acid produced by bacteria.
Distractor Analysis: Acidic substances would accelerate enamel erosion, neutral toothpaste lacks cleaning effectiveness, and corrosive materials would damage oral tissues.
Takeaway: Fluoride in toothpaste strengthens enamel by forming fluorapatite, which resists acid attack better than hydroxyapatite.
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Q.4
WBCS Prelims 2018
Chemical name of vinegar is
A. Sodium nitrate
B. Dilute acetic acid
C. Chloride of lime
D. Calcium
Explanation
Why Correct: Vinegar is 5-8% acetic acid (CH3COOH) in water, produced through fermentation of ethanol by acetic acid bacteria.
Distractor Analysis: Sodium nitrate is NaNO3, a preservative in processed meats. Chloride of lime is Ca(OCl)2, bleaching powder used for disinfection. Calcium is a metallic element (Ca), not vinegar.
Takeaway: Acetic acid glacial is 99-100% pure, while vinegar contains 5-8% acetic acid plus flavor compounds from fermentation.
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Q.5
WBCS Prelims 2015
The compound that cannot be kept in glass vessel because it reacts with glass is
A. HNO3
B. HCl
C. HF
D. HBr
Explanation
Why Correct: Hydrofluoric acid (HF) reacts with silicon dioxide (SiO2) in glass to form silicon tetrafluoride gas and water, dissolving the glass. The reaction is: SiO2 + 4HF -> SiF4 + 2H2O.
Distractor Analysis: Nitric acid (HNO3) is a strong oxidizing acid but does not attack glass significantly. Hydrochloric acid (HCl) is a strong acid but does not react with glass. Hydrobromic acid (HBr) is similar to HCl and does not attack glass.
Takeaway: HF is stored in plastic containers like polyethylene or Teflon, never in glass. It also causes severe tissue burns that penetrate deeply.
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Q.6
WBCS Prelims 2014
Washing soda is the common name for
A. Sodium carbonate
B. Calcium carbonate
C. Sodium bicarbonate
D. Sodium hydroxide
Explanation
Why Correct: Washing soda is sodium carbonate decahydrate (Na2CO3·10H2O), a water-softening agent used in laundry and cleaning.
Distractor Analysis: Calcium carbonate (CaCO3) is limestone, chalk, and marble, used in construction and antacids. Sodium bicarbonate (NaHCO3) is baking soda, a leavening agent and mild antacid. Sodium hydroxide (NaOH) is caustic soda, a strong base used in soap making and drain cleaners.
Takeaway: Baking soda (NaHCO3) releases CO2 when heated or mixed with acid, while washing soda (Na2CO3) does not produce gas and is more alkaline.
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Q.7
WBCS Prelims 2013
Muriatic acid used in household work is diluted form of –
A. Acetic acid
B. Hydrochloric acid
C. Oxalic acid
D. Aqua regia
Explanation
Why Correct: Muriatic acid is the common name for commercial-grade hydrochloric acid (HCl), typically diluted to 20-30% concentration for cleaning and descaling.
Distractor Analysis: Acetic acid is vinegar (CH3COOH). Oxalic acid is a cleaning agent for rust stains. Aqua regia is a mixture of concentrated nitric and hydrochloric acids used to dissolve gold.
Takeaway: Hydrochloric acid is also called spirits of salt because it can be produced by reacting salt (NaCl) with sulfuric acid.
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Q.8
WBCS Prelims 2001
Vinegar is a dilute solution of
A. formaldehyde
B. formic acid
C. ethanol
D. acetic acid (CH3COOH)
Explanation
Why Correct: Vinegar contains 4-8% acetic acid (CH3COOH) in water, produced through fermentation of ethanol by acetic acid bacteria.
Distractor Analysis: Formaldehyde is a preservative and disinfectant, not found in vinegar. Formic acid occurs in ant venom and some industrial processes, but vinegar uses acetic acid. Ethanol is the starting material for vinegar production through fermentation, but vinegar itself contains acetic acid.
Takeaway: Acetic acid gives vinegar its sour taste and pungent smell, while the fermentation process converts ethanol to acetic acid via oxidation.
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Q.9
WBCS Prelims 2001
A pair of compounds that cannot exist together in a solution is
A. sodium bicarbonate and caustic soda
B. sodium bicarbonate and water
C. sodium bicarbonate and sodium carbonate
D. sodium carbonate and caustic soda
Explanation
Why Correct: Sodium bicarbonate (NaHCO3) reacts with caustic soda (NaOH) in a neutralization reaction to form sodium carbonate (Na2CO3) and water, preventing coexistence.
Distractor Analysis: Sodium bicarbonate dissolves in water without chemical reaction. Sodium bicarbonate and sodium carbonate can coexist as both are sodium salts in equilibrium. Sodium carbonate and caustic soda can coexist as both are basic compounds without direct reaction.
Takeaway: Bicarbonate ions (HCO3-) act as weak acids that react with strong bases like hydroxide ions (OH-) to form carbonate ions (CO3^2-).
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