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Everyday Chemistry
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Q.1
WBCS Prelims 2022
Q27. Which of the following isotopes is used in dating archaeological findings?
A. 235U92
B. 14C6
C. 3H1
D. 18O8
Explanation
Why Correct: Carbon-14 (14/6 C) decays with a half-life of 5730 years, allowing dating of organic materials up to 50,000 years old.
Distractor Analysis: Uranium-235 dates rocks over millions of years, tritium (3/1 H) traces water movement with a 12.3-year half-life, and oxygen-18 is stable and used in climate studies.
Takeaway: Potassium-argon dating uses K-40 for geological samples older than 100,000 years, while thermoluminescence dates pottery and burnt stones.
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Q.2
WBCS Prelims 2022
Which among the following is present in refrigerator?
A. Carbon dioxide
B. Methane
C. Helium
D. Chlorofluorocarbon
Explanation
Why Correct: Chlorofluorocarbons (CFCs) like R-12 were historically used as refrigerants in refrigerators and air conditioners before being phased out due to ozone depletion.
Distractor Analysis: Carbon dioxide is a greenhouse gas sometimes used as a modern alternative refrigerant. Methane is a natural gas component and greenhouse gas, not used in refrigerators. Helium is an inert gas used in balloons and cryogenics, not as a refrigerant.
Takeaway: Modern refrigerators often use hydrofluorocarbons (HFCs) like R-134a or hydrocarbons like isobutane.
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Q.3
WBCS Prelims 2021
The chopping of an onion makes one cry because of the chemical containing
A. Sulphur
B. Chlorine
C. Bromine
D. Nitrogen
Explanation
Why Correct: Onion cells release sulfoxides and the enzyme alliinase when cut, producing propanethial S-oxide, a volatile sulfur compound that reacts with eye moisture to form sulfuric acid.
Distractor Analysis: Chlorine appears in tear gas (CS gas) and pool disinfectants, not onions. Bromine is a halogen liquid used in flame retardants and pharmaceuticals. Nitrogen dominates amino acids and proteins in onions but doesn't cause tearing; ammonia (NH3) contains nitrogen but irritates lungs, not eyes specifically.
Takeaway: Chilling onions before cutting reduces enzyme activity and volatile sulfur release, while cutting under water or wearing goggles blocks the compound from reaching eyes.
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Q.4
WBCS Prelims 2020
The gas that filled the electric bulb is
A. nitrogen
B. hydrogen
C. carbon dioxide
D. oxygen
Explanation
Why Correct: Modern incandescent bulbs contain inert nitrogen or argon to prevent oxidation of the tungsten filament at high temperatures.
Distractor Analysis: Hydrogen poses explosion risks and reacts with hot metals. Carbon dioxide can form carbon deposits on the filament. Oxygen accelerates filament oxidation and shortens bulb life.
Takeaway: Halogen bulbs use iodine or bromine gases in a regenerative cycle that redeposits evaporated tungsten back onto the filament.
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Q.5
WBCS Prelims 2019
Which of the following is used in beauty parlours for hair setting ?
A. Chlorine
B. Sulphur
C. Phosphorus
D. Silicon
Explanation
Why Correct: Sulphur compounds like ammonium thioglycolate break and reform disulfide bonds in keratin during permanent hair waving and setting treatments.
Distractor Analysis: Chlorine bleaches hair and damages protein structure. Phosphorus has no role in hair cosmetics. Silicon appears in hair serums and conditioners as dimethicone for shine and detangling.
Takeaway: Ammonium thioglycolate at pH 9.2-9.6 reduces disulfide bonds, while hydrogen peroxide at pH 3.5-4.0 reoxidizes them to set the new hair shape.
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Q.6
WBCS Prelims 2019
Which one among the following is the main ingredient in cement ?
A. Gypsum
B. Limestone
C. Clay
D. Ash
Explanation
Why Correct: Limestone (calcium carbonate) provides 60-65% calcium oxide (CaO) after calcination, the primary component of Portland cement.
Distractor Analysis: Gypsum (calcium sulfate) constitutes 2-5% as a setting retarder, clay provides silica and alumina (20-25%), and ash is a supplementary material in some blended cements.
Takeaway: Cement clinker contains four main compounds: tricalcium silicate (C3S), dicalcium silicate (C2S), tricalcium aluminate (C3A), and tetracalcium aluminoferrite (C4AF).
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Q.7
WBCS Prelims 2018
The term PVC used in plastic industry stands for
A. Polyvinyl Chloride
B. Polyvinyl carbonate
C. Phosphor Vanadium Chloride
D. Phospho Vinyl Chloride
Explanation
Why Correct: PVC stands for Polyvinyl Chloride, a thermoplastic polymer synthesized from vinyl chloride monomers with repeating unit (C2H3Cl)n.
Distractor Analysis: Polyvinyl carbonate is not a standard polymer name in industrial chemistry. Phosphor Vanadium Chloride would denote an inorganic compound containing phosphorus, vanadium, and chlorine atoms. Phospho Vinyl Chloride combines phosphorus terminology with vinyl chloride incorrectly.
Takeaway: Common polymer abbreviations include PET (Polyethylene Terephthalate) for bottles, PP (Polypropylene) for containers, and PS (Polystyrene) for packaging.
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Q.8
WBCS Prelims 2018
Plaster of paris is produced by heating
A. Graphite
B. Gypsum
C. Zinc
D. Lead
Explanation
Why Correct: Heating gypsum (calcium sulfate dihydrate) at 120-180°C produces plaster of paris (calcium sulfate hemihydrate) through controlled dehydration.
Distractor Analysis: Graphite is an allotrope of carbon used in electrodes and lubricants. Zinc is a bluish-white metal employed in galvanizing and alloys. Lead is a dense, toxic metal utilized in batteries and radiation shielding.
Takeaway: Plaster of paris hardens by rehydrating to reform gypsum, making it valuable for medical casts, sculptures, and building materials.
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Q.9
WBCS Prelims 2015
Chemically Aspirin is:
A. Acetyl salicylic acid
B. Sodium salicylate
C. Methyl salicylate
D. Ethyl salicylate
Explanation
Why Correct: Aspirin is acetylsalicylic acid, synthesized by acetylating salicylic acid with acetic anhydride. Its IUPAC name is 2-acetoxybenzoic acid.
Distractor Analysis: Sodium salicylate is the sodium salt of salicylic acid, used as an analgesic and anti-inflammatory. Methyl salicylate is oil of wintergreen, used as a topical analgesic and flavoring agent. Ethyl salicylate is an ester used in perfumes and flavors.
Takeaway: Aspirin works by irreversibly inhibiting cyclooxygenase enzymes, reducing prostaglandin synthesis. It has anti-inflammatory, analgesic, and antiplatelet effects.
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Q.10
WBCS Prelims 2013
Whose presence in drinking water is welcome ?
A. K
B. Ca
C. As
D. Fe
Explanation
Why Correct: Calcium (Ca) in moderate amounts contributes to water hardness but provides essential dietary calcium, supporting bone health.
Distractor Analysis: Potassium (K) occurs in water but offers no specific benefit for hardness. Arsenic (As) is a toxic heavy metal contaminant. Iron (Fe) causes metallic taste, staining, and is undesirable in drinking water.
Takeaway: Permanent hardness in water comes from calcium and magnesium sulfates/chlorides, while temporary hardness comes from their bicarbonates.
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Q.11
WBCS Prelims 2012
Which one of the following is a thermoplastic polymer ?
A. Rubber
B. Nylon 6-6
C. PVC
D. Bakelite
Explanation
Why Correct: Polyvinyl chloride (PVC) softens on heating and hardens on cooling repeatedly without chemical change, defining thermoplastic behavior.
Distractor Analysis: Rubber is an elastomer with cross-linking, Nylon 6-6 is a thermoplastic polyamide but the question specifies PVC in parentheses, and Bakelite is a thermosetting phenol-formaldehyde resin.
Takeaway: Common thermoplastics include polyethylene, polypropylene, polystyrene, and PVC, while thermosets include Bakelite, melamine, and epoxy resins.
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Q.12
WBCS Prelims 2011
Vulcanisation is the process of heating rubber with 3 – 5% of
A. Sulphur
B. Lime
C. Potassium permanganate
D. Naphthalene
Explanation
Why Correct: Vulcanisation adds sulphur to natural or synthetic rubber at 140–160°C, creating cross-links between polymer chains that improve elasticity, durability, and heat resistance.
Distractor Analysis: Lime (calcium oxide) treats acidic soils and stabilises construction materials. Potassium permanganate is a strong oxidising agent used in water treatment and as a disinfectant. Naphthalene is an aromatic hydrocarbon used in mothballs and as a precursor in chemical synthesis.
Takeaway: Charles Goodyear discovered vulcanisation in 1839, and the process typically uses 1–5% sulphur, with accelerators like zinc oxide added to speed up the reaction.
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Q.13
WBCS Prelims 2022
The radioactive element used in heart-pacemakers is
A. Uranium
B. Deuterium
C. Plutonium
D. Radium
Explanation
Why Correct: Plutonium-238 powers cardiac pacemakers through radioactive decay heat converted to electricity, providing long-lasting power without battery replacement.
Distractor Analysis: Uranium fuels nuclear reactors but produces harmful gamma radiation. Deuterium is a stable hydrogen isotope used in nuclear fusion. Radium historically illuminated watch dials but emits dangerous alpha particles.
Takeaway: Pu-238 has a half-life of 87.7 years and generates 0.57 watts per gram, making it ideal for medical implants and space probes like Voyager.
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Q.14
WBCS Prelims 2002
Refrigeration helps in food preservation by
A. Killing bacteria and germs
B. Greatly retarding the rates of biochemical reaction
C. Providing a cover of ice over food
D. Stopping enzyme action
Explanation
Why Correct: Low temperatures in refrigeration slow down microbial growth and biochemical reactions (like oxidation and enzymatic browning) that cause food spoilage.
Distractor Analysis: Refrigeration does not kill most bacteria; it only inhibits their reproduction. Ice cover is a method in freezing, not typical refrigeration, and can cause freezer burn. Enzyme action slows but does not stop completely at refrigeration temperatures (0–5°C); freezing is required to halt it.
Takeaway: Freezing (below -18°C) stops microbial growth and enzyme activity entirely, while refrigeration only retards them.
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