HomePYQChemistryMetals & Compounds
Metals & Compounds
30 questions
All (30) Unattempted (30) Skipped (0) Correct (0) Wrong (0)
Q.1
WBCS Prelims 2023
Which is the reducing agent in the thermit reaction carried out for repairing of the railway track?
A. Iron oxide
B. Aluminium metal
C. Aluminium oxide
D. Iron metal
Explanation
Why Correct: Aluminium metal reduces iron oxide to molten iron in the thermit reaction, making aluminium the reducing agent that loses electrons.
Distractor Analysis: Iron oxide is the oxidizing agent that gets reduced to iron. Aluminium oxide forms as a byproduct when aluminium oxidizes. Iron metal is the final product obtained from reduction.
Takeaway: The thermit reaction uses aluminium powder and iron oxide, producing temperatures around 2500°C for welding railway tracks.
Answer or skip previous question to unlock.
Q.2
WBCS Prelims 2022
Bronze is an alloy of
A. Copper and Zinc
B. Tin and Zinc
C. Copper and Tin
D. Iron and Zinc
Explanation
Why Correct: Bronze is primarily an alloy of copper (88-95%) and tin (5-12%), with tin increasing hardness and corrosion resistance compared to pure copper.
Distractor Analysis: Copper and zinc form brass, which has a distinctive yellow color and different mechanical properties. Tin and zinc alone don't form a historically significant alloy - tin often alloys with lead for solder or with copper for bronze. Iron and zinc form galvanized coatings or some specialized alloys, not bronze.
Takeaway: Common alloy compositions: Brass is copper-zinc, bronze is copper-tin, steel is iron-carbon, and solder is typically tin-lead.
Answer or skip previous question to unlock.
Q.3
WBCS Prelims 2021
Solder used for joining metal parts together is an alloy of
A. Fe and Cu
B. Fe and Zn
C. Sn and Cu
D. Sn and Pb
Explanation
Why Correct: Traditional soft solder contains tin (Sn) and lead (Pb), typically in 60:40 or 63:37 ratios, with a melting point around 183-190°C for electrical and plumbing work.
Distractor Analysis: Fe and Cu forms brass when copper combines with zinc, not iron. Fe and Zn creates galvanized steel coating, not a joining alloy. Sn and Cu produces bronze, used for statues, bearings, and marine hardware due to its corrosion resistance.
Takeaway: Modern lead-free solders use tin with silver, copper, or bismuth to meet RoHS regulations, melting between 217-227°C for electronics manufacturing.
Answer or skip previous question to unlock.
Q.4
WBCS Prelims 2020
Potassium permanganate is used to purify water as It is
A. sterilizing
B. oxidizing
C. reducing
D. leaching
Explanation
Why Correct: Potassium permanganate (KMnO4) oxidizes organic impurities, iron, manganese, and hydrogen sulfide in water, removing color, odor, and some pathogens through chemical oxidation.
Distractor Analysis: Sterilizing agents kill all microorganisms, like chlorine or UV radiation, but KMnO4 does not achieve complete sterilization. Reducing agents donate electrons, like sodium thiosulfate, while KMnO4 accepts electrons. Leaching involves extracting substances using a solvent, as in metal ore processing.
Takeaway: KMnO4 gives a pink color in water treatment; excess turns water pinkish-purple, indicating residual oxidant that needs dechlorination with activated carbon.
Answer or skip previous question to unlock.
Q.5
WBCS Prelims 2019
Brass is a mixture of
A. Copper & Zinc
B. Copper & Tin
C. Copper, Nickel & Zinc
D. Copper, Aluminum & Mg
Explanation
Why Correct: Brass is a copper-zinc alloy, typically containing 60-90% copper and 10-40% zinc.
Distractor Analysis: Copper and tin form bronze, not brass. Copper, nickel, and zinc form nickel silver or German silver. Copper, aluminum, and magnesium form various aluminum bronzes or other specialized alloys.
Takeaway: Bronze is copper-tin alloy, while solder is typically tin-lead alloy.
Answer or skip previous question to unlock.
Q.6
WBCS Prelims 2016
Which metal is present in chlorophyll ?
A. Iron
B. Zinc
C. Aluminium
D. Magnesium
Explanation
Why Correct: Magnesium forms the central atom in the chlorophyll porphyrin ring, essential for capturing light energy during photosynthesis.
Distractor Analysis: Iron is the central atom in hemoglobin. Zinc is a cofactor in many enzymes like carbonic anhydrase. Aluminium has no biological role in chlorophyll or photosynthesis.
Takeaway: Chlorophyll a has a methyl group at position 3, while chlorophyll b has an aldehyde group, affecting their light absorption spectra.
Answer or skip previous question to unlock.
Q.7
WBCS Prelims 2014
The most malleable metal is
A. Platinum
B. Silver
C. Iron
D. Gold
Explanation
Why Correct: Gold is the most malleable metal, capable of being hammered into extremely thin sheets without breaking, with one gram able to be beaten into a sheet of about 1 square meter.
Distractor Analysis: Platinum is a dense, corrosion-resistant precious metal used in jewelry and catalytic converters. Silver is the best conductor of electricity among metals and is also malleable but less so than gold. Iron is a strong, magnetic metal that forms steel when alloyed with carbon.
Takeaway: Gold is also the most ductile metal, meaning it can be drawn into the thinnest wires.
Answer or skip previous question to unlock.
Q.8
WBCS Prelims 2011
Brass is an alloy of
A. Iron and Copper
B. Copper and Tin
C. Copper and Aluminium
D. Copper and Zinc
Explanation
Why Correct: Brass contains 60–90% copper and 10–40% zinc, forming a substitutional solid solution where zinc atoms replace copper in the crystal lattice, improving machinability and corrosion resistance.
Distractor Analysis: Iron and copper form alloys like cupronickel used in marine applications and coins. Copper and tin create bronze, historically used for tools and weapons. Copper and aluminium produce aluminium bronze with high strength and corrosion resistance for marine hardware.
Takeaway: Cartridge brass (70% Cu, 30% Zn) is standard for ammunition casings, while naval brass adds 1% tin for better seawater resistance.
Answer or skip previous question to unlock.
Q.9
WBCS Prelims 2007
The white vitriol is
A. FeSO4 ,7H2O
B. ZnSO4 ,7H2O
C. MgSO4 ,7H2,O
D. CuSO4 ,5H2O
Explanation
Why Correct: White vitriol specifically refers to zinc sulfate heptahydrate (ZnSO4·7H2O), used in medicine, agriculture, and as a mordant in dyeing.
Distractor Analysis: FeSO4·7H2O is green vitriol or ferrous sulfate, used in iron supplements and water treatment. MgSO4·7H2O is Epsom salt or magnesium sulfate, used in bath salts and agriculture. CuSO4·5H2O is blue vitriol or copper sulfate, used as a fungicide and in electroplating.
Takeaway: Common vitriols include green (iron), white (zinc), blue (copper), and red (cobalt) sulfates, each with distinct hydrated forms and applications.
Answer or skip previous question to unlock.
Q.10
WBCS Prelims 2007
Iron is not dissolved in
A. Hot dil. H2O4
B. cold dil. HNO3
C. Fuming HNO3
D. None of the above
Explanation
Why Correct: Concentrated nitric acid, especially fuming HNO3, forms a passive iron oxide layer that inhibits further chemical attack.
Distractor Analysis: Hot dilute sulfuric acid reacts with iron to produce ferrous sulfate and hydrogen gas. Cold dilute nitric acid oxidizes iron to ferric nitrate while reducing nitric acid to nitrogen oxides.
Takeaway: Passivation occurs with metals like chromium, aluminum, and titanium in oxidizing environments, enhancing corrosion resistance.
Answer or skip previous question to unlock.
Q.11
WBCS Prelims 2005
Which one of the following is not a metal?
A. Platinum
B. Mercury
C. Nickel
D. Silicon
Explanation
Why Correct: Silicon is a metalloid with intermediate electrical conductivity and covalent bonding, placing it between metals and non-metals.
Distractor Analysis: Platinum is a dense, corrosion-resistant transition metal. Mercury is the only metal liquid at room temperature. Nickel is a ferromagnetic transition metal used in alloys.
Takeaway: The metalloid group includes silicon, germanium, arsenic, antimony, tellurium, and sometimes boron, which exhibit mixed metallic and non-metallic properties.
Answer or skip previous question to unlock.
Q.12
WBCS Prelims 2003
The purest form of iron is
A. Wrought iron
B. Cast iron
C. Iron turning
D. Stainless steel
Explanation
Why Correct: Wrought iron contains 99–99.8% iron with minimal carbon (0.02–0.08%), making it the purest commercial form of iron.
Distractor Analysis: Cast iron has 2–4% carbon and is brittle, used for engine blocks and cookware. Iron turning refers to machining waste or shavings, not a defined material form. Stainless steel is an alloy with chromium (≥10.5%) and often nickel for corrosion resistance.
Takeaway: Steel is an iron-carbon alloy with 0.2–2.1% carbon; increasing carbon increases hardness but reduces ductility. Pure iron (99.9+%) is rarely used commercially due to softness.
Answer or skip previous question to unlock.
Q.13
WBCS Prelims 2002
Which of the following metals is the best conductor of heat and electricity?
A. Sodium
B. Copper
C. Silver (Ag)
D. Potassium
Explanation
Why Correct: Silver has the highest electrical conductivity (6.30x10^7 S/m) and thermal conductivity (429 W/(m·K)) at room temperature among all metals.
Distractor Analysis: Copper ranks second in conductivity after silver. Sodium and potassium are alkali metals with lower conductivity due to their single valence electron and softer crystal structure.
Takeaway: Gold ranks third in conductivity but resists corrosion, making it valuable for electronics contacts despite higher cost.
Answer or skip previous question to unlock.
Q.14
WBCS Prelims 2001
A substance used in metallurgy to remove rock material is called
A. matrix
B. slag
C. flux
D. gangue
Explanation
Why Correct: Flux is added during smelting to react with gangue (unwanted rock material) and form slag, which can be easily separated from the molten metal.
Distractor Analysis: Matrix refers to the surrounding material in which something is embedded, like in geology or composite materials. Slag is the waste product formed when flux reacts with gangue. Gangue is the unwanted rocky material that surrounds the metal ore in its natural state.
Takeaway: The metallurgical sequence is: ore (metal + gangue) + flux → metal + slag, where flux removes gangue by forming slag.
Answer or skip previous question to unlock.
Q.15
WBCS Prelims 2001
In the manufacture of steel by open hearth process cast iron used has no phosphorus but has manganese as an impurity. The furnace should have a lining of
A. magnesia
B. lime
C. silica
D. lime or magnesia
Explanation
Why Correct: Silica (SiO2) lining creates an acidic slag that removes manganese oxide (MnO) as an impurity while preventing phosphorus removal, which requires a basic lining.
Distractor Analysis: Magnesia (MgO) forms a basic lining used when phosphorus removal is needed. Lime (CaO) also produces basic slag for phosphorus elimination. Lime or magnesia would be incorrect because the absence of phosphorus means acidic conditions are required.
Takeaway: In steelmaking, acidic linings (silica) handle sulfur and manganese removal, while basic linings (lime/magnesia) remove phosphorus and silicon.
Answer or skip previous question to unlock.
Q.16
WBPSC Miscellaneous Prelims 2023
Copper is mixed with which metal to form bronze?
A. Tin
B. Iron
C. Silver
D. Gold
Explanation
Why Correct: Bronze is an alloy primarily composed of copper and tin, typically in proportions of 88% copper and 12% tin, though ratios vary for different uses.
Distractor Analysis: Iron mixed with copper produces alloys like cupronickel, not bronze. Silver and gold are precious metals alloyed with copper to create sterling silver or carat gold but do not form bronze. The defining constituent of bronze is tin, which distinguishes it from brass (copper + zinc).
Takeaway: Bronze = copper + tin; Brass = copper + zinc. This is a fundamental metallurgy fact frequently tested in exams and essential for material identification.
Answer or skip previous question to unlock.
Q.17
WBPSC Miscellaneous Prelims 2019
In stainless steel, iron is mixed with
A. Ni and Cr
B. Cu and Cr
C. Ni and Cu
D. Cu and Zn
Explanation
Why Correct: Stainless steel is an alloy of iron with chromium (at least 10.5%) and nickel. Chromium provides corrosion resistance by forming a passive oxide layer, while nickel enhances toughness and formability.
Distractor Analysis: Copper and chromium are not the standard alloying elements for stainless steel; copper is added in some special grades but not as a primary component. Nickel and copper together form alloys like Monel, not stainless steel. Copper and zinc form brass, an alloy of copper and zinc, not related to stainless steel.
Takeaway: The essential alloying elements for stainless steel are iron, chromium, and nickel. The chromium content is key for rust resistance, and nickel improves ductility. Remember the mnemonic: "Stainless = Fe + Cr + Ni".
Answer or skip previous question to unlock.
Q.18
WBPSC Miscellaneous Prelims 2019
What is the percentage of Calcium in Calcium Carbonate? (Molar mass)
A. 50
B. 10
C. 40
D. 100
Explanation
Core Formula/Logic: Mass percentage = (Atomic mass of element / Molar mass of compound) × 100%.
Step-by-Step Solution: Molar mass of CaCO3 = Ca (40) + C (12) + O3 (48) = 100 g/mol. Atomic mass of Ca = 40 g/mol. Percentage = (40/100) × 100 = 40%.
Common Pitfall: A common mistake is miscomputing the molar mass by forgetting the three oxygen atoms or using atomic mass of calcium incorrectly. Selecting 50% by halving the molar mass or 100% by confusing with the molar mass itself are errors.
Shortcut/Takeaway: In CaCO3, calcium always accounts for exactly 40% by mass. Remember: Ca=40, C=12, O3=48 total 100, so Ca is 40%.
Answer or skip previous question to unlock.
Q.19
WBPSC Miscellaneous Prelims 2018
Which one of the following is the World’s most heat resistant material?
A. Hafnium Carbide (HfC)
B. Nano Material (NM)
C. Titanium (TM)
D. None of the above
Explanation
Why Correct: Hafnium Carbide (HfC) has the highest melting point of any known compound at approximately 3900°C, making it the world's most heat resistant material among common refractory carbides.
Distractor Analysis: Titanium melts at 1668°C, far lower; Nano Material is a broad category not a specific material, and no nano material surpasses HfC in heat resistance; None of the above is incorrect because HfC is a valid option.
Takeaway: HfC and tantalum carbide (TaC) are the most refractory materials, with melting points above 3800°C, used in high-temperature applications like rocket nozzles.
Answer or skip previous question to unlock.
Q.20
WBPSC Miscellaneous Prelims 2012
Which of the following acid can dissolve gold?
A. HNO3
B. H2SO4
C. H2SeO4
D. HClO4
Explanation
Why Correct: Gold is a noble metal and resists attack by any single acid. It dissolves only in aqua regia, a 3:1 mixture of concentrated hydrochloric acid and nitric acid. Nitric acid (HNO3) is a component of aqua regia but alone is insufficient; therefore, the question has no correct single-acid option.
Distractor Analysis: H2SO4 (sulfuric acid) is a strong acid but cannot oxidize gold to a soluble form. H2SeO4 (selenic acid) is similar to sulfuric but also ineffective. HClO4 (perchloric acid) is a strong oxidizer but lacks the complexing agents needed to dissolve gold.
Takeaway: Gold dissolution requires both an oxidizer and a complexing agent. Aqua regia (3 HCl : 1 HNO3) forms chloroauric acid (HAuCl4). Memorize: Gold is attacked only by aqua regia.
Answer or skip previous question to unlock.
Q.21
WBPSC Miscellaneous Prelims 2012
Which of the following is an ore of aluminium?
A. Haematite
B. Dolomite
C. Bauxite
D. Carnalite
Explanation
Why Correct: Bauxite is the primary ore of aluminium, containing hydrated alumina (Al2O3·2H2O) from which aluminium is extracted via the Bayer process and Hall-Héroult electrolysis.
Distractor Analysis: Haematite (Fe2O3) is the chief ore of iron, not aluminium. Dolomite (CaMg(CO3)2) is a carbonate mineral used for magnesium and as a flux. Carnalite (KMgCl3·6H2O) is an ore of potassium and magnesium, not aluminium.
Takeaway: Common ores: Bauxite (Al), Haematite (Fe), Galena (Pb), Cinnabar (Hg), Malachite (Cu). Memorise these for exams.
Answer or skip previous question to unlock.
Q.22
WBPSC Miscellaneous Prelims 2011
One of these substances contains no oxygen. Which one?
A. Bauxite
B. Cryolite
C. Dolomite
D. Epsom salt
Explanation
Why Correct: Cryolite (Na3AlF6) is a sodium aluminium fluoride mineral that contains no oxygen atoms. Its chemical formula consists only of sodium, aluminium, and fluorine.
Distractor Analysis: Bauxite (Al2O3·2H2O) is a hydrated aluminium oxide containing abundant oxygen. Dolomite (CaMg(CO3)2) is a carbonate mineral with oxygen in the carbonate groups. Epsom salt (MgSO4·7H2O) is magnesium sulfate heptahydrate, containing oxygen in both the sulfate ion and water of hydration.
Takeaway: Cryolite is the only common ore and flux used in aluminium smelting that is oxygen-free. Its formula Na3AlF6 teaches that not all minerals contain oxygen — fluorides and chlorides may lack it entirely.
Answer or skip previous question to unlock.
Q.23
WBPSC Miscellaneous Prelims 2011
The single acid which dissolves gold is
A. Nitric acid
B. Hydrochloric acid
C. Selenic acid
D. Aqua regia
Explanation
Why Correct: Aqua regia, a mixture of concentrated nitric acid and hydrochloric acid in a 1:3 ratio, dissolves gold because the chloride ions complex with gold to form chloroauric acid (HAuCl4), while nitric acid provides the oxidizing environment.
Distractor Analysis: Nitric acid alone does not react with gold; gold is a noble metal largely inert to nitric acid. Hydrochloric acid does not react with gold at standard conditions. Selenic acid is not typically used for gold dissolution.
Takeaway: Gold requires both an oxidizing agent and a complexing agent for dissolution — aqua regia provides both through HNO3 and HCl.
Answer or skip previous question to unlock.
Q.24
WBPSC Miscellaneous Prelims 2011
Which metal ion will give a chocolate precipitate with the reagent potassium ferrocyanide?
A. Fe3+
B. Zn2+
C. Cu2+
D. Al3+
Explanation
Why Correct: Cu2+ reacts with potassium ferrocyanide to form a chocolate-brown precipitate of cupric ferrocyanide (Cu2[Fe(CN)6]).
Distractor Analysis: Fe3+ produces a deep blue precipitate of Prussian blue (Fe4[Fe(CN)6]3). Zn2+ forms a white precipitate of zinc ferrocyanide. Al3+ does not precipitate with potassium ferrocyanide under normal conditions.
Takeaway: The chocolate-brown precipitate with potassium ferrocyanide is a confirmatory test for Cu2+ ions. Iron(III) gives Prussian blue, a key distinction in qualitative analysis.
Answer or skip previous question to unlock.
Q.25
WBPSC Miscellaneous Prelims 2010
Aluminium phosphate has the formula
A. Al3(PO4)
B. Al3(PO4)2
C. Al(PO4)
D. Al2(PO4)3
Explanation
Why Correct: Aluminium has a +3 oxidation state (Al3+), and phosphate is PO43-. To balance charge, one Al3+ combines with one PO43- to form AlPO4, written as Al(PO4).
Distractor Analysis: Al3(PO4) has total charge +9 and -3, unbalanced. Al3(PO4)2 is +9 and -6, not balanced. Al2(PO4)3 is +6 and -9, not balanced.
Takeaway: Formula of aluminium phosphate is AlPO4; remember that Al is +3 and PO4 is -3, so a 1:1 ratio.
Answer or skip previous question to unlock.
Q.26
WBPSC Miscellaneous Prelims 2010
Copper reduces 1:1 HNO3 to
A. NO
B. NO2
C. N2O4
D. N2O5
Explanation
Why Correct: Dilute nitric acid (1:1 with water) reacts with copper to produce nitric oxide (NO) as the reduction product.
Distractor Analysis: Nitrogen dioxide is produced with concentrated nitric acid. N2O4 is the dimer of NO2, not directly from copper reduction. N2O5 is nitric anhydride, not formed in this reaction.
Takeaway: Concentrated HNO3 gives NO2; dilute HNO3 gives NO; very dilute may give N2O or NH4+.
Answer or skip previous question to unlock.
Q.27
WBPSC Miscellaneous Prelims 2009
Which one of the following is the most soluble in water?
A. Mg(OH)2
B. Sr(OH)2
C. Ca(OH)2
D. Ba(OH)2
Explanation
Why Correct: Solubility of alkaline earth metal hydroxides increases down the group. Ba(OH)2 is the most soluble due to its larger ionic radius and lower lattice energy compared to Mg(OH)2, Ca(OH)2, and Sr(OH)2.
Distractor Analysis: Mg(OH)2 is sparingly soluble (Ksp ~5.6 x 10^-12). Ca(OH)2 is slightly soluble (Ksp ~5.5 x 10^-6). Sr(OH)2 is more soluble than Ca(OH)2 but less than Ba(OH)2. Ba(OH)2 is the most soluble with Ksp ~2.5 x 10^-4 in water.
Takeaway: Solubility of group 2 hydroxides increases down the group: Mg(OH)2 < Ca(OH)2 < Sr(OH)2 < Ba(OH)2. Base strength also increases in the same order.
Answer or skip previous question to unlock.
Q.28
WBPSC Miscellaneous Prelims 2009
Atomic weight of an element is 24 and its atomic number is 12. Therefore its equivalent weight will be:
A. 12
B. 24
C. 16
D. 48
Explanation
Why Correct: Equivalent weight equals atomic weight divided by valency. The element with atomic weight 24 and atomic number 12 is magnesium, which has valency 2. Thus equivalent weight is 24/2 = 12.
Distractor Analysis: 24 is the atomic weight itself, not the equivalent weight. 16 is the atomic weight of oxygen or the equivalent weight of sulfur in some compounds. 48 would be the atomic weight times valency, not divided.
Takeaway: For elements, equivalent weight = atomic weight / valency. Valency is determined from the group or common oxidation state.
Answer or skip previous question to unlock.
Q.29
WBPSC Miscellaneous Prelims 2007
The metal used in Galvanisation is
A. Iron
B. Silver
C. Zinc
D. Copper
Explanation
Why Correct: Galvanisation coats iron/steel with zinc to prevent rusting via sacrificial protection. Zinc corrodes preferentially.
Distractor Analysis: Iron is the base metal being protected; silver and copper are more expensive and not used for galvanisation.
Takeaway: Galvanisation uses zinc; the process also protects the underlying metal even if the coating is scratched.
Answer or skip previous question to unlock.
Q.30
WBPSC Miscellaneous Prelims 2007
Quick Lime is
A. CaCO3
B. CaO
C. CaCl2
D. CaH2
Explanation
Why Correct: Quick lime is chemically calcium oxide (CaO), produced by thermal decomposition of limestone (CaCO3).
Distractor Analysis: CaCO3 is limestone or calcite (not quick lime). CaCl2 is calcium chloride, a desiccant. CaH2 is calcium hydride, a hydride salt. None of these are quick lime.
Takeaway: Quick lime (CaO) reacts with water to form slaked lime (Ca(OH)2). Lime cycle: CaCO3 -> CaO (quicklime) + CO2; CaO + H2O -> Ca(OH)2 (slaked lime).
Sign in to save progress

Sign in to Papersetters

Save your progress, unlock Smart Review, and track your performance.

Study
PYQ PYQ Plus Practice Smart Review Highlights Mock Test