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Metals & Compounds
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Q.1
WBCS Prelims 2022
Bronze is an alloy of
A. Copper and Zinc
B. Tin and Zinc
C. Copper and Tin
D. Iron and Zinc
Explanation
Why Correct: Bronze is primarily an alloy of copper (88-95%) and tin (5-12%), with tin increasing hardness and corrosion resistance compared to pure copper.
Distractor Analysis: Copper and zinc form brass, which has a distinctive yellow color and different mechanical properties. Tin and zinc alone don't form a historically significant alloy - tin often alloys with lead for solder or with copper for bronze. Iron and zinc form galvanized coatings or some specialized alloys, not bronze.
Takeaway: Common alloy compositions: Brass is copper-zinc, bronze is copper-tin, steel is iron-carbon, and solder is typically tin-lead.
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Q.2
WBCS Prelims 2021
Solder used for joining metal parts together is an alloy of
A. Fe and Cu
B. Fe and Zn
C. Sn and Cu
D. Sn and Pb
Explanation
Why Correct: Traditional soft solder contains tin (Sn) and lead (Pb), typically in 60:40 or 63:37 ratios, with a melting point around 183-190°C for electrical and plumbing work.
Distractor Analysis: Fe and Cu forms brass when copper combines with zinc, not iron. Fe and Zn creates galvanized steel coating, not a joining alloy. Sn and Cu produces bronze, used for statues, bearings, and marine hardware due to its corrosion resistance.
Takeaway: Modern lead-free solders use tin with silver, copper, or bismuth to meet RoHS regulations, melting between 217-227°C for electronics manufacturing.
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Q.3
WBCS Prelims 2020
Potassium permanganate is used to purify water as It is
A. sterilizing
B. oxidizing
C. reducing
D. leaching
Explanation
Why Correct: Potassium permanganate (KMnO4) oxidizes organic impurities, iron, manganese, and hydrogen sulfide in water, removing color, odor, and some pathogens through chemical oxidation.
Distractor Analysis: Sterilizing agents kill all microorganisms, like chlorine or UV radiation, but KMnO4 does not achieve complete sterilization. Reducing agents donate electrons, like sodium thiosulfate, while KMnO4 accepts electrons. Leaching involves extracting substances using a solvent, as in metal ore processing.
Takeaway: KMnO4 gives a pink color in water treatment; excess turns water pinkish-purple, indicating residual oxidant that needs dechlorination with activated carbon.
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Q.4
WBCS Prelims 2019
Brass is a mixture of
A. Copper & Zinc
B. Copper & Tin
C. Copper, Nickel & Zinc
D. Copper, Aluminum & Mg
Explanation
Why Correct: Brass is a copper-zinc alloy, typically containing 60-90% copper and 10-40% zinc.
Distractor Analysis: Copper and tin form bronze, not brass. Copper, nickel, and zinc form nickel silver or German silver. Copper, aluminum, and magnesium form various aluminum bronzes or other specialized alloys.
Takeaway: Bronze is copper-tin alloy, while solder is typically tin-lead alloy.
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Q.5
WBCS Prelims 2016
Which metal is present in chlorophyll ?
A. Iron
B. Zinc
C. Aluminium
D. Magnesium
Explanation
Why Correct: Magnesium forms the central atom in the chlorophyll porphyrin ring, essential for capturing light energy during photosynthesis.
Distractor Analysis: Iron is the central atom in hemoglobin. Zinc is a cofactor in many enzymes like carbonic anhydrase. Aluminium has no biological role in chlorophyll or photosynthesis.
Takeaway: Chlorophyll a has a methyl group at position 3, while chlorophyll b has an aldehyde group, affecting their light absorption spectra.
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Q.6
WBCS Prelims 2014
The most malleable metal is
A. Platinum
B. Silver
C. Iron
D. Gold
Explanation
Why Correct: Gold is the most malleable metal, capable of being hammered into extremely thin sheets without breaking, with one gram able to be beaten into a sheet of about 1 square meter.
Distractor Analysis: Platinum is a dense, corrosion-resistant precious metal used in jewelry and catalytic converters. Silver is the best conductor of electricity among metals and is also malleable but less so than gold. Iron is a strong, magnetic metal that forms steel when alloyed with carbon.
Takeaway: Gold is also the most ductile metal, meaning it can be drawn into the thinnest wires.
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Q.7
WBCS Prelims 2011
Brass is an alloy of
A. Iron and Copper
B. Copper and Tin
C. Copper and Aluminium
D. Copper and Zinc
Explanation
Why Correct: Brass contains 60–90% copper and 10–40% zinc, forming a substitutional solid solution where zinc atoms replace copper in the crystal lattice, improving machinability and corrosion resistance.
Distractor Analysis: Iron and copper form alloys like cupronickel used in marine applications and coins. Copper and tin create bronze, historically used for tools and weapons. Copper and aluminium produce aluminium bronze with high strength and corrosion resistance for marine hardware.
Takeaway: Cartridge brass (70% Cu, 30% Zn) is standard for ammunition casings, while naval brass adds 1% tin for better seawater resistance.
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Q.8
WBCS Prelims 2007
The white vitriol is
A. FeSO4 ,7H2O
B. ZnSO4 ,7H2O
C. MgSO4 ,7H2,O
D. CuSO4 ,5H2O
Explanation
Why Correct: White vitriol specifically refers to zinc sulfate heptahydrate (ZnSO4·7H2O), used in medicine, agriculture, and as a mordant in dyeing.
Distractor Analysis: FeSO4·7H2O is green vitriol or ferrous sulfate, used in iron supplements and water treatment. MgSO4·7H2O is Epsom salt or magnesium sulfate, used in bath salts and agriculture. CuSO4·5H2O is blue vitriol or copper sulfate, used as a fungicide and in electroplating.
Takeaway: Common vitriols include green (iron), white (zinc), blue (copper), and red (cobalt) sulfates, each with distinct hydrated forms and applications.
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Q.9
WBCS Prelims 2007
Iron is not dissolved in
A. Hot dil. H2O4
B. cold dil. HNO3
C. Fuming HNO3
D. None of the above
Explanation
Why Correct: Concentrated nitric acid, especially fuming HNO3, forms a passive iron oxide layer that inhibits further chemical attack.
Distractor Analysis: Hot dilute sulfuric acid reacts with iron to produce ferrous sulfate and hydrogen gas. Cold dilute nitric acid oxidizes iron to ferric nitrate while reducing nitric acid to nitrogen oxides.
Takeaway: Passivation occurs with metals like chromium, aluminum, and titanium in oxidizing environments, enhancing corrosion resistance.
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Q.10
WBCS Prelims 2005
Which one of the following is not a metal?
A. Platinum
B. Mercury
C. Nickel
D. Silicon
Explanation
Why Correct: Silicon is a metalloid with intermediate electrical conductivity and covalent bonding, placing it between metals and non-metals.
Distractor Analysis: Platinum is a dense, corrosion-resistant transition metal. Mercury is the only metal liquid at room temperature. Nickel is a ferromagnetic transition metal used in alloys.
Takeaway: The metalloid group includes silicon, germanium, arsenic, antimony, tellurium, and sometimes boron, which exhibit mixed metallic and non-metallic properties.
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Q.11
WBCS Prelims 2003
The purest form of iron is
A. Wrought iron
B. Cast iron
C. Iron turning
D. Stainless steel
Explanation
Why Correct: Wrought iron contains 99–99.8% iron with minimal carbon (0.02–0.08%), making it the purest commercial form of iron.
Distractor Analysis: Cast iron has 2–4% carbon and is brittle, used for engine blocks and cookware. Iron turning refers to machining waste or shavings, not a defined material form. Stainless steel is an alloy with chromium (≥10.5%) and often nickel for corrosion resistance.
Takeaway: Steel is an iron-carbon alloy with 0.2–2.1% carbon; increasing carbon increases hardness but reduces ductility. Pure iron (99.9+%) is rarely used commercially due to softness.
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Q.12
WBCS Prelims 2002
Which of the following metals is the best conductor of heat and electricity?
A. Sodium
B. Copper
C. Silver (Ag)
D. Potassium
Explanation
Why Correct: Silver has the highest electrical conductivity (6.30x10^7 S/m) and thermal conductivity (429 W/(m·K)) at room temperature among all metals.
Distractor Analysis: Copper ranks second in conductivity after silver. Sodium and potassium are alkali metals with lower conductivity due to their single valence electron and softer crystal structure.
Takeaway: Gold ranks third in conductivity but resists corrosion, making it valuable for electronics contacts despite higher cost.
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Q.13
WBCS Prelims 2001
In the manufacture of steel by open hearth process cast iron used has no phosphorus but has manganese as an impurity. The furnace should have a lining of
A. magnesia
B. lime
C. silica
D. lime or magnesia
Explanation
Why Correct: Silica (SiO2) lining creates an acidic slag that removes manganese oxide (MnO) as an impurity while preventing phosphorus removal, which requires a basic lining.
Distractor Analysis: Magnesia (MgO) forms a basic lining used when phosphorus removal is needed. Lime (CaO) also produces basic slag for phosphorus elimination. Lime or magnesia would be incorrect because the absence of phosphorus means acidic conditions are required.
Takeaway: In steelmaking, acidic linings (silica) handle sulfur and manganese removal, while basic linings (lime/magnesia) remove phosphorus and silicon.
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