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Q.1
WBCS Prelims 2023
Which is the reducing agent in the thermit reaction carried out for repairing of the railway track?
A. Iron oxide
B. Aluminium metal
C. Aluminium oxide
D. Iron metal
Explanation
Why Correct: Aluminium metal reduces iron oxide to molten iron in the thermit reaction, making aluminium the reducing agent that loses electrons.
Distractor Analysis: Iron oxide is the oxidizing agent that gets reduced to iron. Aluminium oxide forms as a byproduct when aluminium oxidizes. Iron metal is the final product obtained from reduction.
Takeaway: The thermit reaction uses aluminium powder and iron oxide, producing temperatures around 2500°C for welding railway tracks.
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Q.2
WBCS Prelims 2016
Which among the following gas was leaked during the Bhopal gas tragedy in 1984 ?
A. Methyl isocyanides
B. Methyl isocyanate
C. Methyl isochloride
D. Methyl isochlorate
Explanation
Why Correct: Methyl isocyanate (MIC, CH3NCO) leaked from the Union Carbide pesticide plant in Bhopal on December 2-3, 1984, causing the world's worst industrial disaster.
Distractor Analysis: Methyl isocyanides are organic compounds with the -NC group. Methyl isochloride (chloromethane) is a refrigerant and solvent. Methyl isochlorate does not exist as a stable compound.
Takeaway: The Bhopal disaster led to the enactment of the Environment Protection Act (1986) and stricter industrial safety regulations in India.
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Q.3
WBCS Prelims 2013
One of the breakthroughs of Acharya P. C. Roy was to synthesize the following compound :
A. HgCl2
B. NH4NO2
C. Hg2Cl2
D. H2O4
Explanation
Why Correct: Acharya Prafulla Chandra Roy first synthesized ammonium nitrite (NH4NO2) in 1896, a landmark achievement in Indian chemistry.
Distractor Analysis: HgCl2 is mercuric chloride (corrosive sublimate). Hg2Cl2 is calomel (mercurous chloride). H2O4 is not a standard chemical formula; it might be a misrepresentation of hydrogen peroxide (H2O2) or other peroxides.
Takeaway: Acharya P.C. Roy also founded Bengal Chemicals & Pharmaceuticals, India's first pharmaceutical company.
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Q.4
WBCS Prelims 2012
Proteins are detected by
A. Molish’s test
B. Biuret test
C. DNP test
D. Benedict’s test
Explanation
Why Correct: Biuret test uses alkaline copper sulfate to form violet complex with peptide bonds, specifically detecting proteins and peptides with at least two peptide bonds.
Distractor Analysis: Molish's test identifies carbohydrates via alpha-naphthol reaction, DNP test detects amino groups in amino acids, and Benedict's test reduces copper(II) to copper(I) oxide for reducing sugars.
Takeaway: Ninhydrin test detects amino acids and proteins with free amino groups, producing purple color, while xanthoproteic test identifies aromatic amino acids through nitration.
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Q.5
WBCS Prelims 2008
Succinic acid dehydrogenase to give
A. Malic acid
B. Formic acid
C. Iso-citric acid
D. Fumaric acid
Explanation
Why Correct: Succinic acid undergoes dehydrogenation via succinate dehydrogenase in the Krebs cycle, losing two hydrogen atoms to form fumaric acid.
Distractor Analysis: Malic acid forms from fumaric acid via fumarase hydration. Formic acid is a simpler carboxylic acid not directly produced in this step. Iso-citric acid precedes succinic acid in the Krebs cycle, forming from citrate.
Takeaway: The Krebs cycle sequence is: citrate -> iso-citrate -> alpha-ketoglutarate -> succinyl-CoA -> succinate -> fumarate -> malate -> oxaloacetate.
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Q.6
WBCS Prelims 2005
Which one of the following is in the mixture of sympathetic ink?
A. Cobalt chloride and water
B. Zinc chloride and water
C. Magnesium chloride and water
D. None of the above
Explanation
Why Correct: Cobalt chloride dissolved in water forms a sympathetic ink that appears nearly invisible when dry and turns blue when hydrated.
Distractor Analysis: Zinc chloride solutions serve as wood preservatives and deodorants. Magnesium chloride solutions are used for dust control and food processing.
Takeaway: Sympathetic inks also include lemon juice (revealed by heat), phenolphthalein (revealed by alkaline solution), and copper sulfate (revealed by ammonia).
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Q.7
WBCS Prelims 2001
The most abundant ions in the Bay of Bengal water are
A. Na+ and Cl-
B. H+ and OH-
C. Mg2+ and SO42-
D. Fe2+ and Cl-
Explanation
Why Correct: Seawater contains sodium (Na+) and chloride (Cl-) ions at approximately 10,800 mg/L and 19,400 mg/L respectively, making them the most abundant ions by far.
Distractor Analysis: H+ and OH- ions exist in very low concentrations in neutral seawater (pH ~8.1). Mg2+ and SO42- are the second and third most abundant cations and anions respectively, but at much lower concentrations than Na+ and Cl-. Fe2+ is present only in trace amounts in seawater.
Takeaway: The major ions in seawater follow a consistent order: Cl- > Na+ > SO42- > Mg2+ > Ca2+ > K+, accounting for over 99% of dissolved solids.
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Q.8
WBCS Prelims 2001
Phosgene is a common name of
A. phosphorus trichloride
B. phosphorus oxychloride
C. phosphine
D. Carbonyl dichloride
Explanation
Why Correct: Phosgene is the common name for carbonyl dichloride (COCl2), a highly toxic gas used historically as a chemical weapon and industrially in polymer production.
Distractor Analysis: Phosphorus trichloride (PCl3) is a colorless liquid used as a chlorinating agent. Phosphorus oxychloride (POCl3) is a colorless liquid used as a chlorinating agent and in semiconductor manufacturing. Phosphine (PH3) is a toxic, flammable gas used as a fumigant and in semiconductor doping.
Takeaway: Phosgene's chemical formula COCl2 reveals it contains carbon, oxygen, and chlorine, distinguishing it from phosphorus compounds.
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Q.9
WBCS Prelims 2001
A substance used in metallurgy to remove rock material is called
A. matrix
B. slag
C. flux
D. gangue
Explanation
Why Correct: Flux is added during smelting to react with gangue (unwanted rock material) and form slag, which can be easily separated from the molten metal.
Distractor Analysis: Matrix refers to the surrounding material in which something is embedded, like in geology or composite materials. Slag is the waste product formed when flux reacts with gangue. Gangue is the unwanted rocky material that surrounds the metal ore in its natural state.
Takeaway: The metallurgical sequence is: ore (metal + gangue) + flux → metal + slag, where flux removes gangue by forming slag.
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Q.10
WBCS Prelims 2001
What are potato ores?
A. Potato of Namital and Himachal Pradesh
B. HYV seed potato raised in irrigated tracts of W.B.
C. Nodules of a variety of minerals found on the sea beds
D. Ores of nuclear minerals
Explanation
Why Correct: Potato ores refer to polymetallic nodules found on deep ocean floors, containing manganese, nickel, copper, and cobalt, named for their irregular, potato-like shape.
Distractor Analysis: Namital and Himachal Pradesh produce agricultural potatoes, not mineral ores. High-yielding variety seed potatoes are cultivated in West Bengal and other regions for food. Nuclear mineral ores include uranium-bearing minerals like pitchblende, found in terrestrial mines.
Takeaway: The Clarion-Clipperton Zone in the Pacific Ocean holds the largest known deposits of these nodules, raising interest in deep-sea mining for critical metals.
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Q.11
WBCS Prelims 2000
Corrosion is a form of _______ erosion.
A. Mechanical
B. Chemical
C. Biological
D. Biophysical
Explanation
Why Correct: Corrosion involves electrochemical oxidation reactions that degrade metals, exemplified by iron rusting (4Fe + 3O2 + 6H2O -> 4Fe(OH)3).
Distractor Analysis: Mechanical erosion involves physical forces like abrasion, impact, or wear. Biological erosion involves living organisms like bacteria, fungi, or plant roots. Biophysical erosion combines biological and physical processes but is not a standard classification for corrosion.
Takeaway: Galvanization applies a zinc coating that sacrificially corrodes before iron, while painting creates oxygen and moisture barriers to prevent corrosion.
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