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Periodic Table & Periodicity
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Q.1
WBCS Prelims 2023
According to Newlands law of octaves, beryllium resembles which of the following elements?
A. Sodium
B. Magnesium
C. Calcium
D. Aluminium
Explanation
Why Correct: Newlands' Law of Octaves states that every eighth element has similar properties when arranged by atomic weight. Beryllium (4th) resembles magnesium (4+8=12th) in the arrangement.
Distractor Analysis: Sodium is the first element of the next period and resembles lithium. Calcium resembles strontium in the next octave. Aluminium resembles boron in the previous octave.
Takeaway: Newlands' arrangement was limited to lighter elements and was superseded by Mendeleev's periodic table which accounted for all elements.
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Q.2
WBCS Prelims 2017
The strongest electropositive element is
A. Cs
B. Li
C. Mg
D. K
Explanation
Why Correct: Cesium (Cs) has the lowest ionization energy and largest atomic radius among alkali metals, making it the most electropositive element, meaning it loses electrons most readily to form positive ions.
Distractor Analysis: Lithium (Li) has the highest ionization energy among alkali metals, making it the least electropositive. Magnesium (Mg) is an alkaline earth metal with higher ionization energy than alkali metals. Potassium (K) is electropositive but less than cesium due to smaller atomic size.
Takeaway: Electropositivity increases down a group in the periodic table due to increasing atomic radius and decreasing ionization energy, with francium being theoretically the most electropositive but cesium being the most electropositive naturally occurring element.
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Q.3
WBCS Prelims 2006
Which among the following is paramagnetic?
A. H2O
B. NO (Nitric oxide)
C. CO2
D. SO2
Explanation
Why Correct: Nitric oxide (NO) has an unpaired electron in its molecular orbital configuration, making it paramagnetic and attracted to magnetic fields.
Distractor Analysis: Water (H2O) has all electrons paired in covalent bonds, making it diamagnetic. Carbon dioxide (CO2) has a linear structure with all electrons paired. Sulfur dioxide (SO2) has a bent structure with all electrons paired in molecular orbitals.
Takeaway: Paramagnetism requires unpaired electrons, while diamagnetism occurs when all electrons are paired; O2 is another common paramagnetic molecule with two unpaired electrons.
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Q.4
WBCS Prelims 2002
Which one of the following is an element?
A. Table salt
B. Water
C. Graphite
D. Glass
Explanation
Why Correct: Graphite is an allotrope of carbon, a pure substance that cannot be broken down into simpler substances by chemical means.
Distractor Analysis: Table salt is sodium chloride, a compound of sodium and chlorine. Water is H2O, a compound of hydrogen and oxygen. Glass is an amorphous solid mixture of silica, soda, and lime.
Takeaway: Elements are listed on the periodic table; compounds contain two or more elements chemically combined in fixed ratios.
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Q.5
WBCS Prelims 2000
Which of the following are called Noble gases?
A. Oxygen and Hydrogen
B. Oxygen and Argon
C. Argon and Neon
D. Hydrogen and NeonWBCS Syllabus Guide
Explanation
Why Correct: Argon and Neon belong to Group 18 elements with full valence electron shells, making them chemically inert.
Distractor Analysis: Oxygen and hydrogen are reactive nonmetals that form water and numerous compounds. Oxygen combines readily with most elements. Hydrogen, though the lightest element, participates in acid-base and reduction-oxidation reactions.
Takeaway: The complete noble gas series includes helium, neon, argon, krypton, xenon, and radon, all characterized by extremely low chemical reactivity.
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Q.6
WBCS Prelims 2012
Gold has an extraordinarily high density than silver, the reason is :
A. Higher mass number of gold
B. Higher atomic number of gold
C. High screening effect
D. Lanthanide contraction
Explanation
Why Correct: Lanthanide contraction causes gold (atomic number 79) to have a smaller atomic radius than expected for its period, packing atoms more densely and increasing density to 19.3 g/cc compared to silver's 10.49 g/cc.
Distractor Analysis: Higher mass number refers to total nucleons but doesn't directly determine density in solids. Higher atomic number indicates more protons but doesn't explain the density difference between gold and silver. High screening effect reduces effective nuclear charge and would increase atomic size, which would decrease density.
Takeaway: Lanthanide contraction affects elements from period 6 onward, making gold, platinum, and mercury denser than their period 5 counterparts (silver, palladium, cadmium).
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Q.7
WBPSC Miscellaneous Prelims 2019
Among Na+, Fe2+, Co3+ and Zn2+ which is/are not transition metal ions?
A. Na+ and Co3+
B. Fe2+ and Co3+
C. Fe2+ and Zn2+
D. Na+ and Zn2+
Explanation
Why Correct: Transition metal ions require a partially filled d subshell in their common oxidation states. Na+ has electron configuration [Ne] (no d electrons) and Zn2+ has [Ar] 3d10 (completely filled d subshell), so neither qualifies.
Distractor Analysis: Fe2+ and Co3+ both have partially filled d orbitals (Fe2+: d6, Co3+: d6), making them transition metal ions. Therefore, any combination that includes Fe2+ or Co3+ as non-transition is incorrect. The correct identification includes only Na+ and Zn2+.
Takeaway: The defining criterion is an incomplete d subshell in any common oxidation state. Zn2+ (d10) and group 1/2 ions are classic non-transition examples.
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Q.8
WBPSC Miscellaneous Prelims 2012
An atom of an element differs from an atom of one of its isotopes in the number of
A. Neutrons in the nucleus
B. Protons in the nucleus
C. Valence electrons
D. Protons outside the nucleus
Explanation
Why Correct: Isotopes of an element have identical numbers of protons but different numbers of neutrons in the nucleus.
Distractor Analysis: Protons in the nucleus are fixed for a given element and do not vary among isotopes. Valence electrons depend on the chemical state, not on isotope identity. Protons never reside outside the nucleus in a neutral atom.
Takeaway: The neutron count is the sole distinction between isotopes; the mass number (protons + neutrons) changes while the atomic number remains constant.
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Q.9
WBPSC Miscellaneous Prelims 2012
Which of the following pairs is from the same group periodic table?
A. Mg, Ca
B. Mg, K
C. Mg, Cu
D. Mg, I
Explanation
Why Correct: Mg (magnesium) and Ca (calcium) belong to Group 2 (alkaline earth metals) of the periodic table. Both have two valence electrons and similar chemical properties.
Distractor Analysis: Mg and K (potassium) are from different groups: Mg is Group 2, K is Group 1. Mg and Cu (copper) differ: Mg is Group 2, Cu is Group 11. Mg and I (iodine) are far apart: Mg is a metal in Group 2, I is a halogen in Group 17.
Takeaway: Elements in the same group have the same number of valence electrons. Group 1: alkali metals; Group 2: alkaline earth metals; Group 17: halogens; Group 18: noble gases.
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Q.10
WBPSC Miscellaneous Prelims 2012
Which of the following pairs is isoelectronic?
A. N2, CO
B. NO, CO
C. CO, CN-
D. O2, CN-
Explanation
Why Correct: N2 has 14 electrons (7 from each N) and CO has 14 electrons (6 from C, 8 from O), making them isoelectronic.
Distractor Analysis: NO has 15 electrons, not matching CO's 14. O2 has 16 electrons, not matching CN-'s 14. Note that CO and CN- also have 14 electrons, making option C another correct isoelectronic pair, but the classic pair is N2 and CO.
Takeaway: Isoelectronic species share identical total electron counts. Common 14-electron species include N2, CO, CN-, and C2^2-. Memorize this series.
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Q.11
WBPSC Miscellaneous Prelims 2012
Tick out the odd combination
A. Cu, Ag, Au
B. Na, K, Rb
C. Zn, Cd, Hg
D. F, Si, I
Explanation
Why Correct: Groups A, B, and C each contain elements from a single periodic group: Group 11 (coinage metals), Group 1 (alkali metals), and Group 12 respectively. Option D mixes a halogen (F), a metalloid (Si), and another halogen (I), making it the only set without a common group.
Distractor Analysis: The combination Cu, Ag, Au consists of Group 11 transition metals known as coinage metals. Na, K, Rb are all Group 1 alkali metals with similar chemical reactivity. Zn, Cd, Hg belong to Group 12 and share properties like volatile nature and low melting points. F, Si, I are from Groups 17, 14, and 17 respectively, so they do not belong to a single group.
Takeaway: In periodic table grouping questions, check if all elements in the set belong to the same group (vertical column). Coinage metals (Group 11), alkali metals (Group 1), and Group 12 metals are common homogeneous sets, while mixing halogens with other non-halogens creates an odd combination.
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Q.12
WBPSC Miscellaneous Prelims 2011
The element which form amphoteric oxide?
A. Bismuth
B. Antimony
C. Phosphorus
D. Sodium
Explanation
Why Correct: Antimony (Sb) forms an amphoteric oxide, Sb2O3, which reacts with both acids (forming antimony salts) and bases (forming antimonites). This property arises from its intermediate position between metals and non-metals.
Distractor Analysis: Bismuth oxide (Bi2O3) is predominantly basic, not amphoteric. Phosphorus oxides (P4O10) are acidic. Sodium oxide (Na2O) is strongly basic.
Takeaway: Among group 15 elements, amphoteric character peaks at arsenic and antimony. Antimony is the one often tested. Also remember aluminum, zinc, and lead form amphoteric oxides.
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Q.13
WBPSC Miscellaneous Prelims 2010
Elements in group ‘0’ of the periodic table are called
A. alkali metal
B. halogens
C. chalcogens
D. noble gases
Explanation
Why Correct: Group 0 (now Group 18) of the periodic table contains the noble gases: helium, neon, argon, krypton, xenon, and radon.
Distractor Analysis: Alkali metals are Group 1. Halogens are Group 17. Chalcogens are Group 16. Noble gases are the correct Group 18 elements.
Takeaway: Group 0/18 = noble gases. They have completely filled valence shells, making them inert.
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Q.14
WBPSC Miscellaneous Prelims 2009
Of the following nuclei, which two have an equal numbers of neutrons?
A. Ne20, Ne21
B. C12, N14
C. C12, N13
D. Li7, Be9
Explanation
Why Correct: Number of neutrons = atomic mass - atomic number. For C12: 12-6=6; for N13: 13-7=6. So they both have 6 neutrons.
Distractor Analysis: Ne20 (10 n) and Ne21 (11 n) differ. C12 (6 n) and N14 (7 n) differ. Li7 (4 n) and Be9 (5 n) differ.
Takeaway: Isotopes of the same element have same protons but different neutrons; here C12 and N13 are different elements but same neutron number (isotones). Remember: Isotones have same neutron count.
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Q.15
WBPSC Miscellaneous Prelims 2009
The number of electrons in the outermost orbit of the element of atomic number 15 is:
A. 1
B. 3
C. 5
D. 7
Explanation
Why Correct: Phosphorus (atomic number 15) has electronic configuration 1s2 2s2 2p6 3s2 3p3. The outermost shell (n=3) contains 5 electrons.
Distractor Analysis: 1 electron corresponds to alkali metals like sodium; 3 electrons to boron group like aluminum; 7 electrons to halogens like chlorine. None of these are phosphorus.
Takeaway: For main group elements, the number of valence electrons equals the group number. Phosphorus is in group 15, thus 5 valence electrons.
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Q.16
WBPSC Miscellaneous Prelims 2009
Has chlorine any isotope?
A. No
B. Two
C. Three
D. Four
Explanation
Why Correct: Chlorine has two stable isotopes: chlorine-35 (75.78%) and chlorine-37 (24.22%).
Distractor Analysis: "No" is incorrect because chlorine does have isotopes. Three and four are incorrect; chlorine has only two naturally occurring stable isotopes, though several radioactive isotopes exist.
Takeaway: Common elements with two stable isotopes include chlorine (35,37), copper (63,65), and silver (107,109).
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Q.17
WBPSC Miscellaneous Prelims 2008
Neutrons in an atom:
A. Are equal to the number of electrons and protons
B. Revolve about the nucleus in fixed orbit
C. Contribute to nuclear charge
D. Vary in number with different isotope
Explanation
Why Correct: Neutrons help stabilize the nucleus, and their number determines the isotope of an element. Isotopes of the same element have the same number of protons but different numbers of neutrons, so the neutron number varies.
Distractor Analysis: Option A is false because the number of neutrons is not necessarily equal to the sum of electrons and protons (mass number = protons+neutrons). Option B is false because only electrons revolve around the nucleus; neutrons reside in the nucleus. Option C is false because nuclear charge is determined solely by protons.
Takeaway: For any element, the number of neutrons = mass number - atomic number. Isotopes differ only in neutron count, e.g., C-12 (6 neutrons), C-13 (7), C-14 (8).
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Q.18
WBCS prelims 2024
Mass of atom is determined by
A. Proton + Neutron
B. Proton + electron
C. Neutron + Electron
D. Proton + Neutron + Electron
Explanation
Why Correct: The mass of an atom is concentrated in its nucleus, which contains protons and neutrons. Electrons have negligible mass (approximately 1/1836th of a proton), so they do not contribute meaningfully to the atomic mass. Therefore, atomic mass is effectively the sum of protons and neutrons.
Distractor Analysis: Proton + electron ignores neutrons, which are essential for mass. Neutron + Electron ignores protons, which are also essential. Proton + Neutron + Electron incorrectly includes electrons, whose mass is negligible and not counted in atomic mass calculations.
Takeaway: The number of protons defines the element (atomic number), while the sum of protons and neutrons defines the mass number. Isotopes of an element differ only in neutron count, which changes the mass number but not the atomic number.
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